Abstract

Understanding lowermost stratosphere (LMS) ozone variability is an important topic in the trends and climate assessment communities because of feedbacks among changing temperature, dynamics, and ozone. LMS evaluations are usually based on satellite observations. Free tropospheric (FT) ozone asses... Show moreUnderstanding lowermost stratosphere (LMS) ozone variability is an important topic in the trends and climate assessment communities because of feedbacks among changing temperature, dynamics, and ozone. LMS evaluations are usually based on satellite observations. Free tropospheric (FT) ozone assessments typically rely on profiles from commercial aircraft. Ozonesonde measurements constitute an independent data set encompassing both LMS and FT. We used Southern Hemisphere Additional Ozonesondes (SHADOZ) data (5.8°N-14°S) from 1998 to 2019 in the Goddard Multiple Linear Regression model to analyze monthly mean FT and LMS ozone changes across five well-distributed tropical sites. Our findings: (a) both FT (5-15 km) and LMS (15-20 km) ozone trends show marked seasonal variability. (b) All stations exhibit FT ozone increases in February-May (up to 15%/decade) when the frequency of convectively driven waves have changed. (c) After May, monthly ozone changes are both positive and negative, leading to mean trends of +(1-4)%/decade, depending on station. (d) LMS ozone losses reach (4-9)%/decade midyear, correlating with an increase in TH as derived from SHADOZ radiosonde data. (e) When the upper FT and LMS are defined by tropopause-relative coordinates, the LMS ozone trends all become insignificant. Thus, the 20-year decline in tropical LMS ozone reported in recent satellite-based studies likely signifies a perturbed tropopause rather than chemical depletion. The SHADOZ-derived ozone changes highlight regional and seasonal variability across the tropics and define a new reference for evaluating changes derived from models and satellite products over the 1998-2019 period. Show less