Abstract

Photolytic production rates of NO, NO₂ and OH radicals in snow and the total absorption spectrum due to impurities in snowpack have been calculated for the Ocean-Atmosphere-Sea-Ice-Snowpack (OASIS) campaign during Spring 2009 at Barrow, Alaska. The photolytic production rate and snowpack absorpti... Show morePhotolytic production rates of NO, NO₂ and OH radicals in snow and the total absorption spectrum due to impurities in snowpack have been calculated for the Ocean-Atmosphere-Sea-Ice-Snowpack (OASIS) campaign during Spring 2009 at Barrow, Alaska. The photolytic production rate and snowpack absorption cross-sections were calculated from measurements of snowpack stratigraphy, light penetration depths (e-folding depths), nadir reflectivity (350-700 nm) and UV broadband atmospheric radiation. Maximum NOx fluxes calculated during the campaign owing to combined nitrate and nitrite photolysis were calculated as 72 nmol m⁻² h⁻¹ for the inland snowpack and 44 nmol m⁻² h⁻¹ for the snow on sea-ice and snowpack around the Barrow Arctic Research Center (BARC). Depth-integrated photochemical production rates of OH radicals were calculated giving maximum OH depth-integrated production rates of -160 nmol m⁻² h⁻¹ for the inland snowpack and -110 - 120 nmol m⁻² h⁻¹ for the snow around BARC and snow on sea-ice. Light penetration (e-folding) depths at a wavelength of 400 nm measured for snowpack in the vicinity of Barrow and snow on sea-ice are -9 cm and 14 cm for snow 15 km inland. Fitting scaled HULIS (HUmic-LIke Substances) and black carbon absorption cross-sections to the determined snow impurity absorption cross-sections show a "humic-like" component to snowpack absorption, with typical concentrations of 1.2-1.5 μgC g⁻¹. Estimates of black carbon concentrations for the four snowpacks are -40 to 70 ng g⁻¹ for the terrestrial Arctic snowpacks and -90 ng g⁻¹ for snow on sea-ice. Show less