Jack Fishman, Susan Solomon, and Paul Crutzen reported on studies they have carried out on world-wide distribution of ozone, concluding that a major source of ozone in the lower atmosphere seems to be industrialization and human activities.
Civilization a major ozone source, scientists say
1978-09-12
University Corporation for Atmospheric Research
archival document
Ozone
Information Office Records
https://aspace.archives.ucar.edu/repositories/2/resources/7
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